Archive for the tag: chemistry

Water Chemistry: Hydration Shells

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Why do we need hydration? Water is the main substance in our bodies, making up more than 50% of a person’s body weight, and it’s directly involved in every biochemical reaction in each cell in our body. Find our full video library only on Osmosis: http://osms.it/more.

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Hydration of alkynes | Alkenes and Alkynes | Organic chemistry | Khan Academy

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Reaction between a terminal alkyne, a strong acid, and mercury (II) sulfate. Using Mark’s rule to determine the regiochemistry of addition, and the mechanism of acid-catalyzed tautomerization. Created by Jay.

Watch the next lesson: https://www.khanacademy.org/science/organic-chemistry/alkenes-alkynes/alkyne-reactions/v/hydroboration-oxidation-of-alkynes?utm_source=YT&utm_medium=Desc&utm_campaign=organicchemistry

Missed the previous lesson? https://www.khanacademy.org/science/organic-chemistry/alkenes-alkynes/alkyne-reactions/v/hydrohalogenation-of-alkynes?utm_source=YT&utm_medium=Desc&utm_campaign=organicchemistry

Organic Chemistry on Khan Academy: Carbon can form covalent bonds with itself and other elements to create a mind-boggling array of structures. In organic chemistry, we will learn about the reactions chemists use to synthesize crazy carbon based structures, as well as the analytical methods to characterize them. We will also think about how those reactions are occurring on a molecular level with reaction mechanisms. Simply put, organic chemistry is like building with molecular Legos. Let’s make some beautiful organic molecules!

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Chad covers the Hydration of Alkynes in this lesson. He begins with a review of the three alkene hydration reactions: 1) acid-catalyzed hydration (Markovnikov), 2) oxymercuration-demercuration (Markovnikov), and 3) hydroboration-oxidation (anti-Markovnikov). He then relates to these three alkene reactions the two alkyne hydration reactions: 1) acid-catalyzed hydration (Markovnikov) and 2) hydroboration-oxidation (anti-Markovnikov). He shows that the addition of one equivalent of H2O across the alkyne results in an enol which tautomerizes to either a ketone or an aldehyde. Chad concludes the lesson by showing the mechanisms for Keto-Enol Tautomerization, both acid-catalyzed and base-catalyzed which commonly appear on undergraduate exams covering the alkyne material.

If you want all my study guides, quizzes, and practice exams, check out my premium course at https://www.chadsprep.com/organic-chemistry-course-youtube

00:00 Lesson Introduction
00:33 Review of the Hydration of Alkenes
01:40 Acid-Catalyzed Hydration of Alkynes (Markovnikov)
05:56 Hydroboration-Oxidation of Alkynes (anti-Markovnikov)
09:36 Hydration of Internal Alkynes
11:33 Keto-Enol Tautomerization
13:22 Keto-Enol Tautomerization Mechanism (Acid-Catalyzed)
14:37 Keto-Enol Tautomerization Mechanism (Base-Catalyzed)

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